Please add this code in your wplms-customizer.php file present in your wplms customizer plugin.
add_filter('wplms_instructing_courses_endpoint','custom_slug_for_instructing_courses',9); function custom_slug_for_instructing_courses(){ return 'custom_link'; }
Please change the custom_link accordingly.
Please do not forget to re-save permalinks after applying this code (it requires permalink structure to be re-saved).